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Diaquabis[5-(1H-tetrazol-5-ylamino-κN4)tetrazolato-κN1]manganese(II) dihydrate

✍ Scribed by Lin, Jiao-Min ;Guan, Yang-Fan ;Dong, Wen

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
665 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Mn(C 2 H 2 N 9 ) 2 (H 2 O) 2 ]Á2H 2 O, has been prepared under hydrothermal conditions. The Mn II atom, lying on an inversion center, is coordinated in an octahedral geometry defined by four N atoms from two di-1H-tetrazol-5ylaminate ligands in the equatorial plane and two water molecules in the axial positions. The complex molecules are linked into a three-dimensional network through O-HÁ Á ÁN, N-HÁ Á ÁO and N-HÁ Á ÁN hydrogen bonds.

Related literature

For a related copper(II) complex of bistetrazolylimine, see: Friedrich et al. (2005).

Experimental Crystal data [Mn(C 2 H 2 N 9 ) 2 (H 2 O) 2 ]Á2H 2 O M r = 431.26 Orthorhombic, Pbca a = 14.8048 (12) A b = 6.8674 (6) A c = 15.1623 (12) A ˚V = 1541.6 (2) A ˚3 Z = 4 Mo K radiation = 0.92 mm À1 T = 296 (2) K 0.24 Â 0.19 Â 0.12 mm Data collection Bruker SMART APEX CCD areadetector diffractometer Absorption correction: multi-scan (SADABS; Sheldrick, 1996) T min = 0.798, T max = 0.891 23612 measured reflections 1764 independent reflections 1148 reflections with I > 2(I) R int = 0.084 Refinement R[F 2 > 2(F 2 )] = 0.052 wR(F 2

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