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Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)manganese(II)

✍ Scribed by Li, Jin-Min


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
977 KB
Volume
63
Category
Article
ISSN
1600-5368

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The Zn atom of the title complex, [Zn(NCS)~2~(C~7~H~8~N~4~O)~2~(H~2~O)~2~] or [Zn(SCN)~2~(H-Pysc)~2~(H~2~O)~2~] [H-Pysc = __N__-aminocarbonyl-__N__′-(3-pyridylmethylene)hydrazine], derived from the condensation of pyridine-3-carbaldehyde and semicarbazone, is located at a crystallographic centre of

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In red crystal of the title compound, [Mn(NCS) 2 (C 6 H 8 -N 2 O 2 ) 2 (H 2 O) 2 ]Á2H 2 O, the Mn II atom lies on an inversion centre and assumes a distorted octahedral coordination geometry. Hydrogen bonds consolidate the crystal structure.