metal-organic papers m106 Xie, He, Zhou andZhu [Co(C 8 H 4 NO) 2 (C 12 H 8 N 2 )(H 2 O) 2 ] Acta Cryst. (2004). E60, m105±m107
Diaquabis(1,10-phenanthroline)cobalt(II) diorotate 2.25-hydrate
✍ Scribed by Bulut, Ahmet ;İçbudak, Hasan ;Yeşilel, Okan Zafer ;Ölmez, Halis ;Büyükgüngör, Orhan
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 373 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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The title compound, [Mn(C~7~H~4~O~5~S)(C~12~H~8~N~2~)~2~(H~2~O)]·4H~2~O, which was obtained by the reaction of MnCl~2~ with sodium hydrogen 3-sulfobenzoate and 1,10-phenanthroline, is a monomer. The coordination polyhedron of the Mn atom is a distorted octahedron. π–π Interactions between neighborin
In the title complex salt, [Mn(C 12 H 8 N 2 ) 2 (H 2 O) 2 ](C 7 H 4 O 5 S)Á-6.5H 2 O, the coordination geometry about the Mn II atom is distorted octahedral, defined by four N atoms from two 1,10phenanthroline ligands and two O atoms from two water molecules. O-HÁ Á ÁO hydrogen-bonding interactions