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Di-μ-iodido-bis[bis(cyclohexyldiphenylphosphine-κP)silver(I)]

✍ Scribed by Young, John F. ;Yap, Glenn P. A.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
603 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Ag 2 I 2 (C 18 H 21 P) 4 ], has a dimeric structure located on a twofold rotation axis with each tetrahedral Ag I ion coordinated by two terminal phosphines and bridged by iodide ligands. Although this structural motif has been reported in bromide-and chloride-silver complexes, this is the first reported dimeric iodide-silver complex with monodentate phosphine.

Related literature

Background information on monodentate phosphine-AgX (X = Br, Cl) adducts can be found in Attar et al. (1991),

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