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(±)-Di-μ-chlorido-(μ-N,N′-{[3,3′-methylenebis(2,4,6-trimethyl-3,1-phenylene)]dimethylene}bis(2-methylpropan-2-amine))bis[chloridopalladium(II)]

✍ Scribed by Chahen, Ludovic ;Therrien, Bruno ;Süss-Fink, Georg

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
390 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title dinuclear palladium complex, [Pd~2~Cl~4~(C~29~H~46~N~2~)], the terminal ligands adopt an anti configuration, with an intramolecular metal–metal distance of 3.3625 (5) Å. The dinuclear palladium complex adopts a V-shaped conformation, with a dihedral angle of 152.67 (3)° between the two chloride-bridged PdNCl~3~ square-planar systems. The benzene rings in the chelating amine ligand are at an angle of 74.9 (1)° with respect to each other. The complex is the first example of chloride-bridged dinuclear palladium complex with a bidentate secondary amine ligand.

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