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Deuterium Kinetic Isotope Effects and Mechanism of the Thermal Isomerization of Bicyclo[4.2.0]oct-7-ene to 1,3-Cyclooctadiene

✍ Scribed by Baldwin, John E.; Gallagher, Sarah S.; Leber, Phyllis A.; Raghavan, Anuradha S.; Shukla, Rajesh

Book ID: 118130635
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 232 KB
Volume: 69
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo040220l

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The ring opening of cis-bicyclo[4.2.0] act-7-ene, t, to c&, cis-1,3cyclooctadiene, 2 has been thoroughly studied in the last few years. 1,2 The reaction proceeds at a reasonable rate only at temperatures near 250°. The