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Computational Study and Analysis of the Kinetic Isotope Effects of the Rearrangement of cis -Bicyclo[4.2.0]oct-7-ene to cis,cis -Cycloocta-1,3-diene

✍ Scribed by Silva López, Carlos; Nieto Faza, Olalla; de Lera, Ángel R.


Book ID
126957114
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
89 KB
Volume
8
Category
Article
ISSN
1523-7060

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The conrotatory ring opening of cis-bicy
✍ John S. McConaghy Jr; Jordan J. Bloomfield 📂 Article 📅 1969 🏛 Elsevier Science 🌐 French ⚖ 189 KB

The ring opening of cis-bicyclo[4.2.0] act-7-ene, t, to c&, cis-1,3cyclooctadiene, 2 has been thoroughly studied in the last few years. 1,2 The reaction proceeds at a reasonable rate only at temperatures near 250°. The