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The conrotatory ring opening of cis-bicyclo[4.2.0] Oct-7-ene to cis, trans-1,3-cyclooctadiene, II. A kinetic treatment

✍ Scribed by Jordan J. Bloomfield; John S. McConaghy Jr.; A.G. Hortmann

Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
204 KB
Volume
10
Category
Article
ISSN
0040-4039

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✦ Synopsis

In the precediny paper' it was shown that cis-bicyclo[4.2.01 act-7-ene,

1, does open to c&, trans-1,3-cyclooctadiene, 2, (by trapping the diene) at temperatures as low as llO".

πŸ“œ SIMILAR VOLUMES

The conrotatory ring opening of cis-bicy
The conrotatory ring opening of cis-bicyclo[4.2.0] Oct-7-ene. I. Trapping cis, trans-1,3-cyclooctadiene with dimethyl acetylenedicarboxylate.
✍ John S. McConaghy Jr; Jordan J. Bloomfield πŸ“‚ Article πŸ“… 1969 πŸ› Elsevier Science 🌐 French βš– 189 KB

The ring opening of cis-bicyclo[4.2.0] act-7-ene, t, to c&, cis-1,3cyclooctadiene, 2 has been thoroughly studied in the last few years. 1,2 The reaction proceeds at a reasonable rate only at temperatures near 250Β°. The