Deuterium isotope effects on the rates of steroid – glucocorticoid receptor interactions
✍ Scribed by Péter ARÁNYI
- Book ID
- 115122200
- Publisher
- John Wiley and Sons
- Year
- 1984
- Tongue
- English
- Weight
- 359 KB
- Volume
- 138
- Category
- Article
- ISSN
- 1432-1327
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📜 SIMILAR VOLUMES
In a recent cosnxurlcation (1) we concluded that reasonable estimates of secotiary deuterium isotope effects caused by rronbotied interactions may be obtained by using Bartell's procedure (2). Particularly disturbing was the discrepancy between the experlmentat isotope effect,
The average rate of mtersystem crossmg from the lowest tnplet state to the ground state increases by a factor of approxunately 2.5 between 2 K and 77 K for tetraphenylchlorin and tetraphenyIchlonn-dr. This observation is discussed interms of radiatronless-transttlon theory. It is also found that, co