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DEUTERIUM ISOTOPE EFFECTS ON THE AIR OXIDATION OF CUMENE

✍ Scribed by Boozer, C. E.; Ponder, B. W.; Trisler, J. C.; Wightman, C. E.


Book ID
127252347
Publisher
American Chemical Society
Year
1956
Tongue
English
Weight
247 KB
Volume
78
Category
Article
ISSN
0002-7863

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Solvent deuterium isotope effect on the
✍ Marı́a JosΓ© PeΓ±alver; JosΓ© Neptuno Rodrı́guez-LΓ³pez; P.A. Garcı́a-Ruiz; Francisc πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 648 KB

A solvent deuterium isotope effect on the catalytic affinity (K(m)) and rate constant (k(cat)) of tyrosinase in its action on 4-tert-butylcatechol (TBC) was observed. Both parameters decreased as the molar fraction of deuterated water in the medium increased, while the k(cat)/K(m) ratio remained con