PHENYL trifluoromethyl carbinols are oxidized by aqueous alkaline permsnganate to the corresponding ketones. We wish to report a kinetic isotope effect of unusual size for the reaction of the 1-deuterio analogs of these compounds. YC6H4CDOHCF3 + 2Mn04-+ 2OH-4 YC H COCF3 + 2Mn0 \* + H20 + RDO 64 4 1-
Deuterium isotope effect and oxidation of labelled alcohols
β Scribed by Manouchehr Saljoughian
- Book ID
- 104944856
- Publisher
- Springer Vienna
- Year
- 1983
- Tongue
- English
- Weight
- 106 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0026-9247
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