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Deuterium isotope effects on silicon-29 chemical shifts

✍ Scribed by Fabienne Berchier; Yi-Ming Pai; William P. Weber; Kenneth L. Servis

Publisher: John Wiley and Sons
Year: 1986
Tongue: English
Weight: 291 KB
Volume: 24
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260240810

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✦ Synopsis

The deuterium isotope effects on the "Si chemical shifts in several organosilanes and siloxanes have been determined. For silanes, the one-bond effects are approximately -0.2ppm per deuterium and follow an additivity relationship. The two-bond effect is small.

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