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Deuterium isotope effects on oxygen-17 chemical shifts

✍ Scribed by Silvio Aime; Enrica Santucci; Roberta Fruttero

Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
282 KB
Volume
24
Category
Article
ISSN
0749-1581

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✦ Synopsis

Large deuterium isotope effects on "0 resonances were observed for six common NMR solvents. Only in the case of acetone did the substitution of deuterium for hydrogen result in a downfield shift. The H/D isotope effect was also detected in a study of the reversible hydration of CH,CHO.

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