Deuterium Isotope Effects on Molecular Dipole Moments by Microwave Spectroscopy
โ Scribed by Muenter, J. S.
- Book ID
- 121407396
- Publisher
- American Institute of Physics
- Year
- 1966
- Tongue
- English
- Weight
- 478 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0021-9606
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The microwave spectrum of the heterodimer EKYbMF is reported, the collinearity of the nuclei establislIed, and ro(N--F) = 2.796 A obtained. From the Stark effect, ~10 (tiCN4iF) = 5.59 r 0.02 D which indicates an enhancement of 0.78 D over the vector sum of the monomer values.
The first-order Stark effect in thcJ = 4 -3, K = 1 transition of the weakly bound dimer H3P...HC"N hasbeenobeserved and n:cosured by pulsed-nozzle Fourier-transform microwavespcctroscopy under the selection rules AM = 0 and AM= 2 1. The electric dipole moment p = 4.046(47) D determined for H3P...HC"