First-order stark effect and electric dipole moment of H3P … HC15N by pulsed-nozzle fourier-transform microwave spectroscopy

✍ Scribed by A.C. Legon; L.C. Willoughby

• Publisher: Elsevier Science
• Year: 1984
• Tongue: English
• Weight: 475 KB
• Volume: 111
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(84)80272-9

✦ Synopsis

The first-order Stark effect in thcJ = 4 -3, K = 1 transition of the weakly bound dimer H3P...HC"N hasbeenobeserved and n:cosured by pulsed-nozzle Fourier-transform microwavespcctroscopy under the selection rules AM = 0 and AM= 2 1. The electric dipole moment p = 4.046(47) D determined for H3P...HC"N has been interpreted in terms of an enhancement AJJ = 0.60 D on dimcr formation.