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Deuterium isotope effect in c.d. of ketones - experiment and theory

โœ Scribed by Walter L. Meyer; A.P. Lobo; Edgar E. Ernstbrunner; Michael R. Giddings; John Hudec

Book ID
107858179
Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
223 KB
Volume
19
Category
Article
ISSN
0040-4039

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Deuterium isotope effects as a conformat
Deuterium isotope effects as a conformational probe in cyclic and acyclic ketones
โœ Stefan Berger; Bernd W. K. Diehl ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 516 KB

Cyclic ketones from cyclobutanone to cyclohexadecanone were labelled with deuterium in the a-position. The deuterium isotope effect on the ''C NMR spectra was measured and in some cases was indicative of perturbation of conformational equilibrium. Similar effects were observed with acyclic ketones.