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Deuterium-induced phase transition of crystalline tolane-d10

✍ Scribed by Yasuhisa Yamamura; Kazuya Saito; Haruo Matsuyama; Isao Ikemoto

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 279 KB
Volume: 256
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(96)00442-3

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✦ Synopsis

A deuterium-induced phase transition has been discovered in a molecular crystal of tolane-d~o by powder X-ray diffraction and differential scanning calorimetry (DSC) experiments. The phase transition is of first order. DSC measurements on solid binary solutions of tolane-h~o and tolane-d~o have shown that there is a critical point on the temperature-composition phase diagram of this binary system.

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