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Determinations of combustion and formation enthalpies of C60and C70

✍ Scribed by Xuwu An; Bin Chen; Jun He

Book ID
105641107
Publisher
SP Science China Press
Year
1998
Tongue
English
Weight
369 KB
Volume
41
Category
Article
ISSN
1674-7291

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πŸ“œ SIMILAR VOLUMES

Enthalpies of combustion and formation o
Enthalpies of combustion and formation of fullerene C60
✍ V.P. Kolesov; S.M. Pimenova; V.K. Pavlovich; N.B. Tamm; A.A. Kurskaya πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 146 KB

The standard molar energy of combustion of pure fullerene C60 was measured using a static-bomb isoperibolic macrocalorimeter: DcUΒ°m = -(25965 2 12) kJβ€’mol -1 . This result was confirmed by recovery of carbon dioxide in the combustion products.

Standard molar enthalpies of combustion
Standard molar enthalpies of combustion and formation of C60
✍ An Xu-wu; He Jun; Bi Zheng πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 152 KB

By using a conventional bomb calorimeter and a technique of burning pure C60 on a gram-scale in a mini-crucible, the standard massic energy of combustion of C60 was determined: DcuΒ°= -(36036.06 2 6.04) Jβ€’g -1 . The corresponding thermodynamic functions at T = 298.15 K were derived for C60: DcHΒ°m(cr)