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Standard molar enthalpies of combustion and formation of C60

✍ Scribed by An Xu-wu; He Jun; Bi Zheng

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
152 KB
Volume
28
Category
Article
ISSN
0021-9614

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✦ Synopsis

By using a conventional bomb calorimeter and a technique of burning pure C60 on a gram-scale in a mini-crucible, the standard massic energy of combustion of C60 was determined: Dcu°= -(36036.06 2 6.04) J•g -1 . The corresponding thermodynamic functions at T = 298.15 K were derived for C60: DcH°m(cr) = -(25970.07 2 9.67) kJ•mol -1 , DfH°m(cr) = (2359.47 2 9.72) kJ•mol -1 , and DfH°m(g) = (2588 2 12) kJ•mol -1 . These results were compared with experimental values in the literature.

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