𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Determination of the standard molar Gibbs energy of formation of lanthanum zirconate by a galvanic cell involving lanthanum β-alumina electrolyte

✍ Scribed by G. Róg; A. Kozłowska-Róg

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
55 KB
Volume
34
Category
Article
ISSN
0021-9614

No coin nor oath required. For personal study only.

✦ Synopsis

The standard molar Gibbs energy of formation of La 2 Zr 2 O 7 from La 2 O 3 and ZrO 2 has been determined in the temperature range 1073 K to 1273 K by the e.m.f. measurements. The solid-state galvanic cell involving lanthanum β-alumina electrolyte was applied. The average values of the standard enthalpy and the standard entropy in the temperature range covered by the e.m.f. measurements have also been estimated. The results have been compared with those obtained by other authors.

📜 SIMILAR VOLUMES

Determination of the standard molar Gibb
Determination of the standard molar Gibbs energy of formation of calcium zirconate by a galvanic cell involving calcium-ion conducting solid electrolyte
✍ G. Róg; M. Potoczek-Dudek 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 69 KB

The standard molar Gibbs energy of formation of CaZrO 3 from CaO and ZrO 2 has been determined by the e.m.f. measurements of a galvanic cell with calcium-ion conducting solid-state electrolyte in the temperature range 1073 K to 1273 K. The average values of the standard enthalpy and the standard ent

Measurement of the standard molar Gibbs
Measurement of the standard molar Gibbs free energy of formation of Ag2S using Ag+β-alumina solid electrolyte
✍ Dominique Bouchard; Christopher W. Bale 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 460 KB

Ag + b-alumina has been employed as a solid electrolyte in order to measure the activities of silver for Ag2S in equilibrium with controlled sulphur atmospheres. Electromotive-force measurements were made in the temperature range 811 K to 1112 K using the galvanic cell: Manipulation of the results

Determination of the standard molar Gibb
Determination of the standard molar Gibbs free energies of formation of the silicates of cobalt and nickel by solid-state galvanic cells involving the CaF2-based composite electrolyte
✍ G. Róg; A. Kozlowska-Róg; M. Bucko; E. Glowacz 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 61 KB

The standard molar Gibbs free energies of formation of Co 2 SiO 4 and Ni 2 SiO 4 have been determined by solid-state galvanic cells in the temperature range 823 K to 1273 K. Calcium fluoride-based composite containing SiO 2 (mole fraction x = 0.05) was applied as a solid electrolyte. The results wer