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Determination of the rate constant of hydroperoxyl radical reaction with phenol

✍ Scribed by Kozmér, Zsuzsanna; Arany, Eszter; Alapi, Tünde; Takács, Erzsébet; Wojnárovits, László; Dombi, András

Book ID
121811542
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
580 KB
Volume
102
Category
Article
ISSN
0969-806X

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Rate constants for hydrogen abstraction
Rate constants for hydrogen abstraction reactions by the hydroperoxyl radical from methanol, ethenol, acetaldehyde, toluene, and phenol
✍ Mohammednoor Altarawneh; Ala'A H. Al-Muhtaseb; Bogdan Z. Dlugogorski; Eric M. Ke 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 381 KB 👁 1 views

An important step in the initial oxidation of hydrocarbons at low to intermediate temperatures is the abstraction of H by hydroperoxyl radical (HO(2)). In this study, we calculate energy profiles for the sequence: reactant + HO(2) → [complex of reactants] → transition state → [complex of products] →