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Effect of solvation on the reaction rate constants of the diphenylaminyl radical with phenols and hydroquinones

✍ Scribed by A. V. Antonov; N. N. Denisov; V. A. Nadtochenko; V. T. Varlamov


Publisher
Springer
Year
2007
Tongue
English
Weight
279 KB
Volume
56
Category
Article
ISSN
1573-9171

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Rate constants of the reactions of OH ra
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The kinetics of the reactions of hydroxy radicals with cyclopropane and cyclobutane has been investigated in the temperature range of 298-492 K with laser flash photolysidresonance fluorescence technique. The temperature dependence of the rate constants is given by k l = (1.17 ? 0.15) x T3'' exp[-(1