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Rate Constants of Hydroperoxyl Radical Addition to Cyclic Nitrones: A DFT Study

✍ Scribed by Villamena, Frederick A.; Merle, John K.; Hadad, Christopher M.; Zweier, Jay L.

Book ID: 118734418
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 204 KB
Volume: 111
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp073615s

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## Abstract Absolute rate constants are reported for the addition of the 1‐[(__tert__‐butoxy)carbonyl]ethyl (= 2‐(1,1‐dimethylethoxy)‐1‐methyl‐2‐oxoethyl) radical ^.^CHMeCO~2~(__t‐__Bu) to several cyclic and monosubstituted alkenes in MeCN as obtained by time‐resolved electron paramagnetic resonanc