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Determination of the Absolute Configuration of 1-Arylethane-1,2-diols by a Nonempirical Analysis of the CD Spectra of Their 4-Biphenylboronates

โœ Scribed by Superchi, Stefano; Donnoli, Maria Irene; Rosini, Carlo


Book ID
126821831
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
71 KB
Volume
1
Category
Article
ISSN
1523-7060

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NMR determination of the absolute config
โœ Hiroki Fukui; Yukiharu Fukushi; Satoshi Tahara ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 218 KB

Each of the chiral 1,2-and 1,3-diols examined was derivatized exclusively to a single diastereomeric acetal by the use of a new axially chiral reagent, 2%-methoxy-1,1%-binaphthalene-8-carbaldehyde (MBC). The absolute configuration of the original 1,2-and 1,3-diols was determined by the NOE correlati