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Determination of Rate Constants for the Activation Step in Atom Transfer Radical Polymerization Using the Stopped-Flow Technique

✍ Scribed by Pintauer, Tomislav; Braunecker, Wade; Collange, Edmond; Poli, Rinaldo; Matyjaszewski, Krzysztof


Book ID
126242077
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
92 KB
Volume
37
Category
Article
ISSN
0024-9297

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## Abstract Summary: The effect of [L]/[Cu^I^] ratio, ligand, the choice of solvent and temperature on the activation rate constants in ATRP with catalyst complexes formed with two pyridylmethanimine ligands [PMI, i.e., __N__‐propyl‐pyridylmethanimine (NPPMI) and __N__‐octyl‐pyridylmethanimine (NOP