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Determination of Activation and Deactivation Rate Constants of Model Compounds in Atom Transfer Radical Polymerization 1

✍ Scribed by Matyjaszewski, Krzysztof; Paik, Hyun-jong; Zhou, Peng; Diamanti, Steve J.

Book ID: 120527550
Publisher: American Chemical Society
Year: 2001
Tongue: English
Weight: 93 KB
Volume: 34
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma010185+

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## Abstract Summary: The effect of [L]/[Cu^I^] ratio, ligand, the choice of solvent and temperature on the activation rate constants in ATRP with catalyst complexes formed with two pyridylmethanimine ligands [PMI, i.e., __N__‐propyl‐pyridylmethanimine (NPPMI) and __N__‐octyl‐pyridylmethanimine (NOP