A Β―ow injection spectrophotometric method for the determination of carbofuran in commercial pesticide formulations was developed. The determination involves on-line hydrolysis of the extracted carbofuran at room temperature with sodium hydroxide. The resulting carbofuran-phenol is coupled with diazo
Determination of paraquat by flow-injection spectrophotometry
β Scribed by Archana Jain; Krishna K. Verma; Alan Townshend
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 472 KB
- Volume
- 284
- Category
- Article
- ISSN
- 0003-2670
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β¦ Synopsis
The solution obtained by oxidizing some of the ascorbic acid to dehydroascorbic acid by reaction with potassium iodate is used as a reagent for the reduction of paraquat to a blue radical cation in the flow-injection spectrophotometric determination of paraquat. A rectilinear calibration graph was obtained over the range 0.1-100 pg ml-' paraquat, and the limit of detection was 20 ng ml-' paraquat (signal-to-noise ratio = 3). This reagent has been found superior to ascorbic acid alone or sodium dithionite because of the lower limit of detection, wide linear range of determination, rapid reaction and high stability.
π SIMILAR VOLUMES
Reactor replacement is proposed as means of realizing different sample residence times in flow-injection analysis. As an application, an improved spectrophotometric determination of cobalt and nickel is proposed. The method exploits differences in reaction rates between cobalt and nickel citrate com
A rapid and sensitive method is described for flow-injection spectrophotometric determination of trace chromium (VI) in natural water. Preconcentration and elution of the trace analyte are achieved through quantitative and rapid adsorption on the surface of nanometer-size TiO 2 (anatase) powders and
An automated flow injection spectrophotometric method has been developed for the rapid, simple, selective, and sensitive determination of selenium (IV) from various pharmaceutical multivitamin and mineral formulations. The method was based on the oxidation of 4-aminoantipyrine (4-amino-l,2-dihydro-1