Hexatriacontane (C 36 ) was exposed to vacuum ultraviolet radiation. The formation of double bonds was investigated by derivatization, i.e. these olefinic structures were transformed by epoxidation in order to determine their number in the molecule. The extent of the reaction was determined by means
Determination of disulfide bonds in highly bridged α-dendrotoxin by matrix-assisted laser desorption/ionization mass spectrometry
✍ Scribed by Hélène Belva; Chrystel Valois; Catherine Lange
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 80 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0951-4198
No coin nor oath required. For personal study only.
✦ Synopsis
A methodology which combines tryptic digestions, 1,4-dithiothreitol reduction, and matrix-assisted laser desorption/ionization mass spectrometry (MALDI-TOF-MS) allows verification of the location of the disulfide bridges in alpha-dendrotoxin (C7-C57, C16-C40 and C32-C53). Copyright 2000 John Wiley & Sons, Ltd.
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