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Determination of absolute rate constants of addition of ethyl radicals to olefins

✍ Scribed by V. E. Myshkin; A. G. Shostenko; P. A. Zagorets; K. G. Markova; A. I. Pchelkin

Book ID
112360099
Publisher
Springer
Year
1977
Tongue
English
Weight
387 KB
Volume
13
Category
Article
ISSN
0040-5760

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An absolute value of k, of ethyl radicals at 860 f 17Β°K of 4.5 X l o 9 M-l.sec-' was determined under VLPP conditions, where the value of k,/k," should be about M. Thus k,"(M-'.sec-') -10' 0 at 860Β°K. An error of as much as a factor of 2 in k, would be surprising, but possible. The value of lO'OM-'