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The Determination of Absolute Rate Constants in Olefinic Oxidations

✍ Scribed by L. Bateman and G. Gee

Book ID
123674750
Publisher
The Royal Society
Year
1948
Tongue
English
Weight
432 KB
Volume
195
Category
Article
ISSN
0962-8444

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Claims have recently been made that absolute rate constants for chain propagation of the unassociated active centers can be made in systems where a high degree of association is present. Anionic polymerization of styrene in nonpolar solvents with lithium as counterion is a typical case. The conditio

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## Abstract Lack of termination in the β€œLiving” polymer systems enables one to determine directly the absolute rate constant of propagation and of copolymerization. Anionic polymerizations in tetrahydrofuran are usually very fast, and a flow technique was developed to determine the rate of these re