Condensation of argon/HF mixtures at 12 I( revealed sharp new 38X.5 and 3702.0 cm-' absorptions which exhibited different growth behaviour on sample warming. hlixed HF/DF samples revealed a single mixed isotopic satellite near the DF counterpart of the former band assigned to (HF)z and a group of sa
Detection of endor spectra of paramagnetic species isolated in solid argon
✍ Scribed by G. Cirelli; A. Russu; R. Wolf; M. Rudin; A. Schweiger; Hs.H. Günthard
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 164 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The ESR and ENDOR spcctm of msthyl rati& and olvanatium dlbcnzenc lsohtcd in xgon m~~cs It 10 K XC presented. The spectra should demonstntc tbt CNDOR sipll may be observed from a wlds variety of pxmu~net~c centers Isohtcd in ra~-g~~s matncrs.
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An infrared matrix isolation study has been performed for sodium and benzene mixtures in solid argon at 9 K. In contrast with the earlier report, sodium was evidenced to form complexes with benzene. Although the exact nature of the complexes is not certain, ab initio quantum mechanical calculation i