Desymmetrization of meso -1,2-Diols via Chiral Lewis Acid-Mediated Ring-Cleavage of 1,3-Dioxolane Derivatives
β Scribed by Kinugasa, Motoharu; Harada, Toshiro; Oku, Akira
- Book ID
- 126302370
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 101 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0002-7863
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Desymmetrization of meso-1,2-Diols via Chiral Oxazaborolidine-Mediated Ring-Cleavage of Acetal Derivatives with Silyl Ketene S,O-Acetal. -The desymmetrization of a variety of meso-1,2-diols is readily achieved by chiral oxazaborolidine-mediated enantioselective ring cleavage of acetals of type syn-
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