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ChemInform Abstract: Enantioselective Ring Cleavage of Dioxane Acetals Mediated by a Chiral Lewis Acid: Application to Asymmetric Desymmetrization of meso-1,3-Diols.

✍ Scribed by Toshiro Harada; Kousuke Sekiguchi; Tomohito Nakamura; Jun Suzuki; Akira Oku

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
33
Category
Article
ISSN
0931-7597

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Desymmetrization of meso-1,2-Diols via Chiral Oxazaborolidine-Mediated Ring-Cleavage of Acetal Derivatives with Silyl Ketene S,O-Acetal. -The desymmetrization of a variety of meso-1,2-diols is readily achieved by chiral oxazaborolidine-mediated enantioselective ring cleavage of acetals of type syn-