Design of a Binaphthyl-Based Axially Chiral Amino Acid as an Organocatalyst for Direct Asymmetric Aldol Reactions
β Scribed by Taichi Kano; Osamu Tokuda; Jun Takai; Keiji Maruoka
- Book ID
- 112005130
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 158 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1861-4728
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## Abstract **Amino sulfonamide catalyst**: A distal proton of the axially chiral amino sulfonamide (__S__)β**1** realized the opposite diastereoselectivity in Mannich and crossβaldol reactions compared with that observed in prolineβcatalyzed reactions. The reactions catalyzed by (__S__)β**1** proc
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