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Design and synthesis of a transition state analogue for the Diels–Alder reaction

✍ Scribed by Paramjit S. Arora; Que N. Van; Michael Famulok; A.J. Shaka; James S. Nowick


Book ID
108480649
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
215 KB
Volume
6
Category
Article
ISSN
0968-0896

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📜 SIMILAR VOLUMES


Endo and exo transition states in the Di
✍ William C. Herndon; Lowell H. Hall 📂 Article 📅 1967 🏛 Elsevier Science 🌐 French ⚖ 278 KB

We have recently determined kinetic parameters for the unimolecular Diels-Alder retrogressions of exe and w-dicyclopentadiene to monomer (1). The activation enthalpies and entropies are aH f (E) 37.4 2 0.3 kcal/mole, hSS (E) + 1.1 2 0.6 e.u., hH + (&) 33.0 2 0.5 kcal/mole, and hSS (endo) \_ -1.9 +