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Derivatives of γ-Valerolactone, 1,4-Pentanediol and 1,4-Di-(β-cyanoethoxy)-pentane 1

✍ Scribed by Christian, Robert V.; Brown, Horace D.; Hixon, R. M.


Book ID
126227548
Publisher
American Chemical Society
Year
1947
Tongue
English
Weight
399 KB
Volume
69
Category
Article
ISSN
0002-7863

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The reaction of 3,4-di-tert-butylthiophene (2) with N-[(p-tolylsulfonyl)imino]phenyliodinane (TsN=IPh) in the presence of Cu(MeCN)4PF6 in MeCN at room temperature provided ), and 1-(p-tolylsulfonyl)-3,4-di-tertbutylpyrrole (5) as the principal products. The use of 2 in a large excess gave 3 in a bet