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6-hydroxymethyl-1,2,4-trioxanes and derivatives: An alternative 1,2,4-trioxane synthesis from β′γ′-unsaturated β-hydroxyhydroperoxides

✍ Scribed by A.J. Bloodworth; Karen A. Johnson


Book ID
103402262
Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
175 KB
Volume
35
Category
Article
ISSN
0040-4039

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Oxy-functionalized 1,2,4-trioxanes or 1,2,4-trioxepanes were produced by either autoxidation of the unsaturated hydroperoxy acetals 1, or the acid-catalyzed cyclization of epoxy hydroperoxides 9 which were readily prepared from 1. By the appropriate choice of cyclization procedure, the structures of