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1-imino and 1,1-diimino derivatives of 3,4-di-tert-butylthiophene

✍ Scribed by Takashi Otani; Yoshiaki Sugihara; Akihiko Ishii; Juzo Nakayama

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
238 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

The reaction of 3,4-di-tert-butylthiophene (2) with N-[(p-tolylsulfonyl)imino]phenyliodinane (TsN=IPh) in the presence of Cu(MeCN)4PF6 in MeCN at room temperature provided ), and 1-(p-tolylsulfonyl)-3,4-di-tertbutylpyrrole (5) as the principal products. The use of 2 in a large excess gave 3 in a better yield of 61%. Results of the X-ray crystallographic analyses of 3 and 4 are also reported.

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