Derivatives of Morpholine. I. Addition to Conjugate Systems. I.
โ Scribed by Stewart, Vincent E.; Pollard, C. B.
- Book ID
- 111906268
- Publisher
- American Chemical Society
- Year
- 1937
- Tongue
- English
- Weight
- 100 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
RhCl(COD)] 2 (2 mol%) catalyzed reactions of alkenylzirconocene chloride complexes to N-Ts, -PO(OEt) 2 and COOR aldimine derivatives were efficiently carried out in dioxane at room temperature to give allylic amine derivatives in excellent yields. This is the first example of the catalytic addition
The reactions of Grignard reagents with methyl 2-acetamidoacrylate in the presente of CuI give fair to good yields of cr-amino esters; the corresponding a-deutero-or a-methyl-derivatives are obtained upon quenching with D+ or CH31, respectively.