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Derivatives of 3-thiocyanophenothiazine Communication 2: Direction of the thiocyanation reaction in 2-chlorophenothiazine

✍ Scribed by A. A. Shtyrlina; D. Kh. Yarmukhametova; K. M. Enikeev; I. É. Ismaev; I. A. Nuretdinov

Book ID
112446025
Publisher
Springer
Year
1983
Tongue
English
Weight
276 KB
Volume
32
Category
Article
ISSN
1573-9171

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Reaction of anodically generated thiocyanogen (NaSCN, LiClO4, MeCN, Pt, 0.9V vs SCE) with 3-alkylsubstituted indoles results preferentially in iso2hiocyanafion at the indole 2position rather than in the expected thiocyanation.