✦ LIBER ✦

Selectivity in the thiocyanation of 3-alkylindoles: an unexpectedly easy access to 2-isothiocyano derivatives

✍ Scribed by Giovanni Palmisano; Elisabetta Brenna; Bruno Danieli; Giordano Lesma; Bruno Vodopivec; Gorgio Fiori

Book ID: 104228580
Publisher: Elsevier Science
Year: 1990
Tongue: French
Weight: 268 KB
Volume: 31
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)97287-3

No coin nor oath required. For personal study only.

✦ Synopsis

Reaction of anodically generated thiocyanogen (NaSCN, LiClO4, MeCN, Pt, 0.9V vs SCE) with 3-alkylsubstituted indoles results preferentially in iso2hiocyanafion at the indole 2position rather than in the expected thiocyanation.

📜 SIMILAR VOLUMES

ChemInform Abstract: Cyclopropyl Buildin

ChemInform Abstract: Cyclopropyl Building Blocks in Organic Synthesis. Part 51. An Easy Access to 1-Azaspiropentane-2-carboxamides — The First Derivatives of a New Type of Amino Acids.

✍ Markus Tamm; Michael Thutewohl; Carsten B. Ricker; M. Teresa Bes; Armin de Meije 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 1 views