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Dependence of the capacity ratio on the composition of the binary mobile phase in liquid—solid adsorption chromatography

✍ Scribed by J. Narkiewicz; M. Jaroniec; M. Borówko; A. Patrykiejew

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
335 KB
Volume
157
Category
Article
ISSN
1873-3778

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Contents 1 Introduction 2 Fundamental Definitions in Liquid-Solid Chromato-3 Oscik's Equation for the Capacity Ratio in LSC with Mixed Mobile Phases graphy (LSC) 3.1 Classical Form of Oscik's Equation 3.2 Determination of Parameters in OScik's Equation 3.3 Modified Form of OScik's Equation

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The recently derived general equation for the capacity ratio has been utilized to study the dependence of selectivity and resolution upon mobile phase composition. This equation accounts for differences in molecular size of solutes and solvents, and for the energetic heterogeneity of the adsorbent s