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Dependence of selectivity and resolution upon composition of the binary mobile phase in LSC

✍ Scribed by Jaroniec, M. ;Suprynowicz-Sieńko, D.

Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
296 KB
Volume
6
Category
Article
ISSN
0935-6304

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✦ Synopsis

The recently derived general equation for the capacity ratio has been utilized to study the dependence of selectivity and resolution upon mobile phase composition. This equation accounts for differences in molecular size of solutes and solvents, and for the energetic heterogeneity of the adsorbent surface. Model calculations illustrating the influence of these factors on the selectivity and resolution are presented and discussed.

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