Excess molar volumes V E m and excess molar heat capacities C E p,m were determined for mixtures of benzonitrile with chlorobenzene, or benzene, or toluene at the temperatures 298.15 K and 303.15 K. For all the systems the values of V E m were negative over the whole range of compositions and values
Density and excess molar volumes of aqueous solutions of morpholine and methylmorpholine at temperatures from 298.15 K to 353.15 K
β Scribed by Y. Maham; ; M. Boivineau; ; A.E. Mather
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 140 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0021-9614
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β¦ Synopsis
Densities of (water + morpholine) and (water + methylmorpholine) have been measured over the full range of compositions at temperatures from 298.15 K to 353.15 K. Density values have been used for calculations of excess molar volumes and partial molar volumes of morpholine and methylmorpholine in the mixtures. The effect of the additional methyl group on the methylmorpholine compared to morpholine is reflected in a lower density value and a more negative excess molar volume.
π SIMILAR VOLUMES
The excess volumes of (an isomer of butanol +1 -chlorobutane) were determined with an Anton-Paar densimeter at the temperatures \(T=298.15 \mathrm{~K}\) and \(313.15 \mathrm{~K}\). Excess volumes are positive over the whole composition range, except for mixtures containing butan-1-ol at both tempera
Excess molar enthalpies H E m and excess molar volumes V E m have been determined for (butane+propan-1-ol) at temperatures (298.15, 323.15, and 348.15) K and at pressures (5, 10, and 15) MPa. The H E m results and the excess molar heat capacity C E p,m are positive, while V E m (x) is s-shaped, chan