𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Delocalization of unpaired electron in anion-radicals ofα,α′-binaphthyl and 9,9′-bianthryl

✍ Scribed by S. P. Solodovnikov; M. I. Kabachnik

Book ID
112421624
Publisher
Springer
Year
1973
Tongue
English
Weight
127 KB
Volume
22
Category
Article
ISSN
1573-9171

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Substituent-Dependent Electron Transfer
Substituent-Dependent Electron Transfer in Radical Anions of 9- and 9,10-Disubstituted 2,7-Dinitro-9,10-dihydro-9,10-ethanoanthracenes
✍ Anthony J. Manny; Robert K. Norris; Paul K. Witting 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 707 KB

Radical anions from a series of 9-substituted-and 9,1O-disubstituted-2,6-dinitro-and 2,7-dinitro-9,10-dihydro-9,10ethanoanthracenes were investigated by EPR spectroscopy at 25 "C. In the case of radical anions of compounds with nitro groups in both the 2-and &positions, hyperfine coupling constants

Generation and intramolecular cyclizatio
Generation and intramolecular cyclization of difluoroalkyl radicals via single electron transfer from the benzeneselemolate anion: Synthesis of α,α-difluoro-γ-lactams
✍ Kenji Uneyama; Takeo Yanagiguchi; Hideki Asai 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 150 KB

## Sewsl a,adiflw1w74scts (2) were pqxucd by radical cycliion of amides (1) wbicb wscinitiatcd by a single electron transfer (SET) process from the bmzneselmolate anion. De&laurion of these lactams (2)gave the umeq&iq a,adifhmn+xcm&yk lactams I$).

Electron Spin Resonance of α-(Alkoxycarb
Electron Spin Resonance of α-(Alkoxycarbonyl)alkyl Radicals in Solution
✍ Wu Lung-min; Hanns Fischer 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 German ⚖ 502 KB

High-resolution ESR. spectra of the radicals CH2COOR, CH3CHCOOR and (CH3)ZCCOOR with R = CH3, CH2CH3, CH (CH,), and C (CH,), in liquid solution confirm planar energy-minimum structures with substantial barriers to internal rotation about the C, CO-bonds (-40 kJ/mol) and partial n-electron delocaliza