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Defining the Catalytic Metal Ion Interactions in the Tetrahymena Ribozyme Reaction †

✍ Scribed by Shan, Shu-ou; Kravchuk, Alexander V.; Piccirilli, Joseph A.; Herschlag, Daniel

Book ID
126401660
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
161 KB
Volume
40
Category
Article
ISSN
0006-2960

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Metal ions and the stereochemistry of ri
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Inversion of configuration at phosphorus during ribozyme-catalyzed cleavage of RNA is usually considered unequivocal proof of in-line attack, but the relevant pseudorotation diagram for formation of the 2('),3(')-cyclic phosphate shows that inversion is not inconsistent with adjacent attack as long