Deconjugative alkylation of the enolate anion derived from ethyl crotonate
β Scribed by J.L. Herrmann; G.R. Kieczykowski; R.H. Schlessinger
- Book ID
- 104247171
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 189 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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O-&y active aLan& WM obtined by anymmtic one carbon A?UL~A~UL treaction. Va&i\_ation 06 the natit 06 the imine moie.ty in the eMatiObdetiV& aLkyLa\_tion 04 Schi.,jfj babe.4 de,tived dhom g.Lycine cawed the enavu%metLic Cicedb -to b&,(-t @om 0 -to 70 %. During the last few years, we have been concern
Results are reported on the regioselective C-deuteriation of a series of enol acetates (derived from the aryl alkyl ketones) using molecular deuterium as the D-source and palladium-on-barium sulphate as the mediator. The results presented highlight potential problems associated with the deuteriation
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