Single-crystal X-ray study T = 120 K Mean '(C±C) = 0.007 A Ê Disorder in solvent or counterion R factor = 0.068 wR factor = 0.201 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Darstellung substituierter 1H-2,3-Dihydro-1,5-benzodiazepine und 2,3-Dihydro-1,5-benzothiazepine
✍ Scribed by Helga Voigt
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 234 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0044-2402
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📜 SIMILAR VOLUMES
Darstellungsmethodc Ausb. in Sb Schinp. i n OC (unikrist . aus) Sunnuenforinel (Yol1nasse ) Anelyscn oben: ber. Wertr unten: gef. Werte r: U N \*) XII. Yitteilung iiber Heterocyclen aus CH-aciden Nitrilen; XI. Mittei. lung: Z. Chem. 6,261 (1966).
In the title compound, C 11 H 14 N 2 O, the diazepine ring adopts a skewed boat conformation. The molecule is stabilized by N-HÁ Á ÁO intermolecular hydrogen bonds, forming a zigzag chain parallel to the b axis.
## Abstract The condensation of α,β‐unsaturated ketones with substituted __o__‐aminothiophenols, obtained by reductive cleavage of the corresponding disulfides in the presence of triphenylphosphine, is an effective method for the synthesis of 2,4‐diaryl‐2,3‐dihydro‐1,5‐benzothiazepines under neutra