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DABCO catalyzed dimerization of α,β-unsaturated ketones and nitriles

✍ Scribed by D. Basavaiah; V.V.L. Gowriswari; T.K. Bharathi

Book ID
108383069
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
130 KB
Volume
28
Category
Article
ISSN
0040-4039

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Activated nickel, produced by the ultrasound-promoted reduction of nickel iodide with lithium, catalyzes the 1,4 addition of phenylsilane to ct, 13-unsaturated ketones and ct, 13 -unsaturated nitriles to give, after hydrolysis, high yields of the products of 1, 2 hydrogenation.