𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Base-Catalyzed Reactions of α,β-Unsaturated Esters and Nitriles. I. Potassium-Catalyzed Dimerization of Ethyl Crotonate 1a

✍ Scribed by Shabtai, Joseph; Pines, Herman

Book ID
126158729
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
431 KB
Volume
30
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Palladium-catalyzed regioselective react
Palladium-catalyzed regioselective reactions of α-acetoxy-β,γ-unsaturated nitriles and γ-acetoxy-α,β-unsaturated ester with nucleophiles
✍ Jiro Tsuji; Hiroaki Ueno; Yuichi Kobayashi; Hiroshi Okumoto 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 120 KB

e-Acetoxy-8,y-unsaturated nitriles react at room temperature with malonates and acetoacetates in the presence of palladium-phosphine complexes as a catalyst to give y-substituted a,8-unsaturated nitriles selectively. Also yacetoxy-a,8-unsaturated ester was attacked at y-position by malonate.